Browsing by Author "Onchieku, James"

Now showing 1 - 2 of 2
  • Publication
    Publication
    Occurrence and distribution of Organochlorine Pesticide Residues in Water and Sediments of Earthen Fish Ponds in South Western Kenya
    (Africa Journals Online, 2019) Nyaundi, Joseph Kiyuka; Getabu, Albert; Onchieku, James; Kinaro, Zachary; Bassa, Samuel; Nyamweya, Chrisphine; Nyaboke, Hilda; Getenga, Zachary
    Persistent organochlorine residues in the environment are a threat to ecological health of aquatic organisms and pose a health risk to both animals and human consumers. Organochlorine pesticides were determined in water and sediments collected during wet and dry season from selected riverine and earthen fish pond sites in high altitude catchment areas within Kuja River (Kenya) between August 2016–May, 2017. Analysis of DDT and metabolites, Hexachlorocyclohexanes (HCHs) isomers and cyclodienes using a gas chromatograph (GC), and electron capture detector (ECD), confirmed using GC - Mass Spectrometry (MS). Mean (± Standard error) results of DDTs, cyclodienes and HCHs in pond waters were:- below detection level (BDL) to 0.27±0.03µg/L, BDL to 0.11±0.00µg/L, and 4.39±1.01µg/L respectively; and BDL to 0.23±0.01µg/L, 1.20±0.005µg/L, and 1.71±0.02µg/L in river water respectively. Sediment mean OCPs contents were significantly (p<0.05) higher for Dieldrin (3.043±0.43µg/kg), Endrin (2.56±0.460µg/kg), Heptachlor (3.61±0.02µg/kg) DDT (2.97±1.32µg/kg), Endosulfan (6.31.27±1.051µg/kg), Methoxychlor (2.15±1.641µg/kg) and Lindane (2.96±1.32µg/kg), respectively. A longitudinal spatial distribution pattern was noted for both water and sediment OCPs contents, demonstrating that cyclodienes are predominant contaminants in point and non-point sources in water courses. The study recommends continuous monitoring of OCPs in upstream catchment areas for informed management and policy decisions on pesticide use.Keywords: Kuja-Migori River; Organic contaminants; Organochlorine Pesticide.
  • Publication
    Publication
    Organochlorine Contaminants in Nile Tilapia, Oreochromis niloticus (Linnaeus 1758) in Densely Populated Areas of South-Western Kenya
    (2020) Nyaundi, Joseph; Getabu, Albert; Mwamburi, Job; Onchieku, James; Kinaro, Zachary; Ogendi, George; Babu, Miruka; Gichuru, Nicholas
    Concentrations of OCP (Organochlorine Pesticide) residues were determined in cultured Nile tilapia (Oreochromis niloticus) fish in target stations within 1st order wetland of River Kuja, Kenya, between February-November, 2017. The aim was to assess the residue levels in wild and pond cultured fish within a heavily populated agricultural area of South Western Kenya. Biota samples were analysed for selected HCHs (Hexachlorocyclohexane) isomers, DDT (Dichlorodiphenyltrichloroethane) and metabolites and cyclodienes pesticide residues using GC-ECD (Gas Chromatography Equipped with Electron Capture Detector). Most of OCPs observed were BDL (Below Detection Limit) to detectable levels. Larger percentages (> 50%) of DDTs and HCHs were BDL and exhibited consistency, with significant (p < 0.05) differences in mean contamination levels in fish within the wetland, with average muscle tissue pesticides concentrate ranging between 0.229-2.541 g/kg for Nile tilapia. Most dominant isomer in target species was Lindane (-HCH) (3.417 ± 0.983 g/kg) and Endosulfans. Mean Endosulfan sulfate was 2.499 ± 0.071 g/kg d.w. and most frequently detected, and Methoxychlor (2.235 ± 1.459 g/kg), respectively. Mean Aldrin and Dieldrin was 2.028 and 0.574 g/kg d.w. Concentration for DDT and its metabolites was 0.27-3.71 g/kg for p, p’-DDE (DichlorodiphenylDichloroEthene), BDL-1.098 for p, p’-DDD (DichloroDiphenylDichloroEthane), and 0.105-3.518 g/kg for p, p’-DDT with significant differences in mean values and ranges whose levels were below the WHO (World Health Organization) maximum acceptable thresholds of 0.2, 2, 20 and 5.0 g/kg in fish and sea food.